Which colored complex is formed between 1/10-phenanthroline and ferrous metal ion is?
The complex of 1,10-phenanthroline with Fe(II) is called ferroin and has been widely used in titrimetric analysis as a redox indicator . 1,10-Phenanthroline forms with Fe(III) a blue complex (λmax 585 nm) which has been used for determining larger amounts of iron.
What is the purpose for using 1/10-phenanthroline?
1,10-Phenanthroline forms a stable complex with Fe(II) ion called ferroin, which is used as an indicator in Fe(II) salt titrations. Ferroin is also used in the determination of other metals, such as nickel, ruthenium, and silver.
What is the molar absorptivity of iron phenanthroline complex?
The molar absorptivity of the complex was calculated as 12570 L•mol-1cm-1 using Beer’s law.
What is the molar absorptivity of iron?
The analytical curve for total iron determination obeys Beer’s law (r = 0.9993), and the value calculated for the average molar absorptivity (2.10×104 L cm-1 mol-1) showed the high potential of this system for analytical applications.
What are the colors of I the complex between phen and Fe2+?
Scheme of Fe–phen complex formation; coordination of an Fe2+ ion with three phen molecules via lone-pair electrons on the N atoms of phen. The red–orange color of the solutions becomes stronger as the Fe concentration increases.
What is the color of phenanthroline?
It is used as a redox indicator with standard potential +1.06 V. The reduced ferrous form has a deep red colour and the oxidised form is light-blue.
What is phenanthroline used for?
Phenanthroline (phen) is a heterocyclic organic compound. It is a white solid that is soluble in organic solvents. It is used as a ligand in coordination chemistry, forming strong complexes with most metal ions.
Why is O phenanthroline used in this lab?
One widely used iron complex is iron(II)-o-phenanthroline, which is orange-red and easy to detect. Like most metal complexation reactions, the metal ion must compete with H3O+ ions, and thus the metal complex will not form in strongly acidic solutions.
How do you calculate molar absorptivity?
The standard equation for absorbance is A = ɛ x l x c, where A is the amount of light absorbed by the sample for a given wavelength, ɛ is the molar absorptivity, l is the distance that the light travels through the solution, and c is the concentration of the absorbing species per unit volume.
How do you calculate the molar absorptivity?
Is fe2+ or phen the limiting reactant?
Similarly, we say that Fe2+ ions are the “limiting reagent” because all of the Fe2+ ions are used up in the reaction and the amount of products formed are limited by the number of Fe2+ ions initially available.